Silica And Phosphate Reactions In The Boiler Drum

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Four Boiler Contaminants that Jeopardize Power Plant

Feb 14, 2014 · Like sodium, silica should be measured at multiple points around the steam system, including the demineralization plant, boiler feedwater, boiler drums, superheater and condenser outlets.

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Water Handbook - Preboiler & Industrial Boiler Corrosion

quicklime-used at a rate of 6 lb/100 ft³ of boiler volume; silica gel-used at a rate of 17 lb/100 ft³ of boiler volume; activated alumina-used at a rate of 27 lb/100 ft³ of boiler volume; The trays are placed in each drum of a water tube boiler, or on the top flues of a fire-tube unit.

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Carry Over From Boiler Drum - Bright Hub Engineering

Oct 10, 2009 · Phosphate residual ppm 5 to 10; pH at 25 deg C 9.1 to 9.8; Silica (Max) ppm - To be controlled on the basis of silica in boiler water and drum pressure relationship to maintain less than 0.02 ppm in steam leaving drum. Carryover from the drum can be of two types: mechanical carryover and vaporous carryover. Mechanical carryover take place in a

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Boiler – Fundamentals and Best Practices

Water tube boiler Multiple drum system low pressure (LP) medium pressure (MP) Silica 6 0 % Condensate 50 Basic Boiler Calculations. Calculate the feedwater composition (impurities) from make up and condensate analysis below Phosphate/Polymer Treatment • Reactions

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Water and Steam chemistry-Deposits and Corrosion-

May 25, 2016 · Water chemistry factors that facilitate cracking include dissolved oxygen and low pH transients associated with, for example, cyclic operation, condenser leaks, and phosphate hideout and hideout-return. Acid phosphate corrosion occurs on the inner steam forming side of boiler tubes by reaction of the steel with phosphate to form maricite (NaFePO4).

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The Importance of Boiler Water and Steam Chemistry

Vaporous silica carryover at a pH of 10.0 is 88% of that at a pH of 8.8. The vaporous silica carryover at a pH of 11.0 is 74% of that at 8.8. The only effective method for preventing excessive silica or other vaporous carryover is reduction of the boiler water concentrations.

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Water Handbook - Steam Purity | SUEZ

Carryover is any solid, liquid, or vaporous contaminant that leaves a boiler steam drum with the steam. In boilers operating at pressures of less than 2000 psig, entrained boiler water is the most common cause of steam contamination. The entrained boiler water contains dissolved solids and can also contain suspended solids.

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why trisodium phosphate dosing in boiler drum – CFBC

Trisodium Phosphate dosing is done in boiler drum which react with scale forming salts like calcium cloride,calcium sulphate. 3 cacl2 + 2 na3 po4 = ca3 (po4)2 +6 nacl the sludge collected in bottom header which can be removed by operating low points drain. phosphate dosing is done to prevent scale formation in boiler

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Boiler Water Treatment

2/18/2014 3 Cheat Sheet - Reactions • Bicarbonate Break: Na 2 HCO 3 + HEAT Na 2 CO 3 + CO 2 + H 2 O • Developed Alkalinity: Na 2 CO 3 + HEAT + 2H 2 O 2NaOH + CO 2 + H 2 O • Brining Reactions: CaCl + Boiler Water CaSO 4 + CaSiO 3 • Phosphate Reactions: Ca 3 (PO 4) 2 Tricalcium Phosphate

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Polyamine Treatment in HP Steam System of an Ammonia …

rium phosphate treatment (EPT) was used for boiler control. Sodium triphosphate with a small amount of sodium hydroxide is added to the steam drum. PO4 concentration and pH are ad-justed within the defined operating range for EPT. Continuous blowdown is normally con-trolled by pH and on rare occasions by the silica concentration.

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water treatment Flashcards | Quizlet

phosphate (PO4) silica (Sio2) what is PH? a measure of the water's acidity or alkalinity. lay trays of moisture absorbing chemicals in the boiler drums 5) close steam and water side the end point is the final stage of a process. it is the point in a titration at which the reaction is complete.

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Ph And Phosphate Concentration In Bfw And Steam Drum

why trisodium phosphate dosing in boiler drum – CFBC Boiler Manufac…

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CHAPTER 39 BOILER WATER TREATMENT

silicate, various forms of iron oxide, silica adsorbed on the previously mentioned precipitates, and alumina (see Table 39.1). If phosphate salts are used to treat the boiler water, calcium will preferentially precipitate as the phosphate before pre-cipitating as the carbonate, and calcium phosphate becomes the most prominent feature of the

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(PDF) Concentration control of silica in water chemical

The effective relations of silica (SiO2) concentration in boiler drum and generated steam, with respect to pH and pressure for a natural circulation water wall tubes (WWTs) high-pressure (158 and

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On-line Silica and Phosphate Measurement White Paper to

ensure high quality feed water is delivered to the boiler. Silica has negligible conductivity and therefore cannot be Used within approximately 50% of power plant drum-type boilers, phosphate

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On-line Silica and Phosphate Measurement White Paper to

ensure high quality feed water is delivered to the boiler. Silica has negligible conductivity and therefore cannot be Used within approximately 50% of power plant drum-type boilers, phosphate

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Phosphate corrosion in high-pressure boilers (Journal

Dec 01, 1995 · Only drum boiler units using phosphate boiler water treatment are included in this study. Information on concentration and transport of chemical impurities and sodium phosphate around drum boiler cycles was collected and correlated with chemical composition of low pressure (LP) turbine deposits collected after the water and steam sampling.

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Silica Monitoring TECHNICAL NOTE On Power Plant

silica found in the boiler. Should the concentration of silica in the drum become too high, then a 'blowdown' is initiated. This is the removal of contaminated water from the boiler. Adequate control of the blowdown is very important. If it is allowed to occur too often, it becomes expensive and inefficient. The silica monitoring in the boiler drum is one parameter

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The Importance of Boiler Water and Steam Chemistry

Vaporous silica carryover at a pH of 10.0 is 88% of that at a pH of 8.8. The vaporous silica carryover at a pH of 11.0 is 74% of that at 8.8. The only effective method for preventing excessive silica or other vaporous carryover is reduction of the boiler water concentrations.

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Silica Analyzer | Phosphate Analyzer

Used within power plant drum-type boilers, phosphate treatment plays two important roles. First, maintaining proper alkalinity within the boiler water. Second, phosphate controls scale build-up for effective blowdown and protection against corrosion. A silica and phosphate analyzer allows the monitoring of phosphate levels to enables reliable

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